GNU Collaborative International Dictionary of English
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Found one definition
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Vicinal (?; 277), a. [L. vicinalis: cf. F. vicinal.]
1. Near; vicine. T. Warton.
[1913 Webster]
2. (Organic Chem.) Having the substituted groups on the same carbon atom.
[PJC]
Vicinal planes (Min.), subordinate planes on a crystal, which are very near to the fundamental planes in angles, and sometimes take their place. They have in general very complex symbols.
[1913 Webster]